A Study of Effect of Dye Structure on Polyelectrolyte Induced Metachromasy
Issue:
Volume 2, Issue 6-2, December 2014
Pages:
1-7
Received:
30 August 2014
Accepted:
7 September 2014
Published:
23 September 2014
Abstract: The interaction of two cationic dyes, namely, Azure B (AB) and Pinacyanol chloride (Pcyn) with an anionic polyelectrolyte, namely, sodium carrageenate (NaCar) has been investigated by Spectrophotometric method. The polymer induced metachromasy in the dyes resulting in the shift of the absorption maxima of the dyes towards shorter wavelengths. The stability of the complexes formed between Azure B and sodium carrageenate was found to be lesser than that formed between Pinacyanol chloride and sodium carrageenate. This fact was further confirmed by reversal studies using alcohols, urea surfactants and electrolytes. The interaction parameters revealed that binding between Azure B and sodium carrageenate was mainly due to electrostatic interaction while that between Pinacyanol chloride and carrageenate is found to involve both electrostatic and hydrophobic forces. The effect of the structure of the dye and its relation to metachromasy has been discussed.
Abstract: The interaction of two cationic dyes, namely, Azure B (AB) and Pinacyanol chloride (Pcyn) with an anionic polyelectrolyte, namely, sodium carrageenate (NaCar) has been investigated by Spectrophotometric method. The polymer induced metachromasy in the dyes resulting in the shift of the absorption maxima of the dyes towards shorter wavelengths. The s...
Show More
A Comparative Study of Metachromasy Induced in Azure B by Anionic Polyelctrolytes
Issue:
Volume 2, Issue 6-2, December 2014
Pages:
8-13
Received:
6 September 2014
Accepted:
23 September 2014
Published:
23 September 2014
Abstract: The interaction of two cationic dyes, namely, Azure B (AB) with an anionic polyelectrolyte, namely, sodium heparinate (NaHep) has been investigated by Spectrophotometric method. The polymer induced metachromasy in the dyes resulting in the shift of the absorption maxima of the dyes towards shorter wavelengths. The stability of the complexes formed between Azure B and sodium alginate was found to be greater than that formed between Azure B and sodium carboxymethylcellulose.This fact was further confirmed by reversal studies using alcohols, urea surfactants and electrolytes.The interaction parametersrevealed that binding between Azure B and anionic poloyelectrolytes was mainly due to electrostaticinteraction.
Abstract: The interaction of two cationic dyes, namely, Azure B (AB) with an anionic polyelectrolyte, namely, sodium heparinate (NaHep) has been investigated by Spectrophotometric method. The polymer induced metachromasy in the dyes resulting in the shift of the absorption maxima of the dyes towards shorter wavelengths. The stability of the complexes formed ...
Show More
