Volume 2, Issue 6-2, December 2014, Page: 8-13
A Comparative Study of Metachromasy Induced in Azure B by Anionic Polyelctrolytes
Nandini Ratnakar, Department of Chemistry, MITE, Moodabidri-574 226 (DK), Karnataka, India
Received: Sep. 6, 2014;       Accepted: Sep. 23, 2014;       Published: Sep. 23, 2014
DOI: 10.11648/j.sjc.s.2014020602.12      View  3876      Downloads  224
The interaction of two cationic dyes, namely, Azure B (AB) with an anionic polyelectrolyte, namely, sodium heparinate (NaHep) has been investigated by Spectrophotometric method. The polymer induced metachromasy in the dyes resulting in the shift of the absorption maxima of the dyes towards shorter wavelengths. The stability of the complexes formed between Azure B and sodium alginate was found to be greater than that formed between Azure B and sodium carboxymethylcellulose.This fact was further confirmed by reversal studies using alcohols, urea surfactants and electrolytes.The interaction parametersrevealed that binding between Azure B and anionic poloyelectrolytes was mainly due to electrostaticinteraction.
Cationic Dye, Metachromasy, Anionicpolyelectrolytes, Electrostatic Interaction, Aggregation
To cite this article
Nandini Ratnakar, A Comparative Study of Metachromasy Induced in Azure B by Anionic Polyelctrolytes, Science Journal of Chemistry. Special Issue: Polyelectrolytes & Dyes. Vol. 2, No. 6-2, 2014, pp. 8-13. doi: 10.11648/j.sjc.s.2014020602.12
A Mitra, R. K Nath,, SBiswas., A. K., Chakraborty, A. K., Panda Mitra A. , J. Photochrem. Photobiol, A: Chem, vol.111, 1997, pp 157.
A.Mitra, A.K.Chakraborty, J.Photochem.Photobiol.A:Chem., vol.178,2006, pp198.
R.W Horbin., Biochemie.Biochem., vol.77, 2002, pp 3.
Bergeron J. A., M. J Singer,. Biophys. Biochem. Cytol. vol.4,1958, pp.433.
M. K. Pal , B. K. Ghosh, Makromol. Chem. vol. 181, 1980, pp1459 .
Norden B., Kubista M., in : B.Samori, E.W.Thulstrup (Eds.), Polarized Spectroscopy of ordered systems, vol.242,Kulwer Academic Publisher, Dordrecht, Holland, 1988.
Sabate R., EsterlichJ., J.Phys.ChemB, vol.107,2003, pp.4137.
von Berlepsch H., Kirstein S., Bottcher, C, Langmuir, vol.18,2002,pp.769.
Sabate R., Gallardo M., De la Maza A., J.Esterlich, Langmuir,vol.17,2001, pp.6433.
Berret J.F., Cristobal G.,Hervel P., Oberdisse J.,Grillo I., vol.E9, Eur.Phys J 2002, pp.301.
Meszaos R., Varga, I.,Gilanyi T.,J.Phys.Chem.B vol.117, 2005, pp.13538.
Monteux C . ,WilliamsC.E., Meunier J., Anthony O., BergeronV., Langmuir Vol.20,2004,pp. 57.
Honda C., Kamizono H.,.Matsumoto K., Endo K., J.Colloid Interface Sci vol.278.2004, , pp.310.
MoulikS.P., GuptaS,.DasA.R., Makromol.Chem,vol.181, 1980,pp. 1459.
Lee J ., Moroi Y,,J.Colloid Interface Sci. 2vol.273,2004, pp.645.
Mesa C.L., J.Colloid Interface Sci . vol.286,2005, pp.148.
Konradi R.,Ruhe J., Macromolecules vol.38,2005, pp.6140.
VilletiM., BorsaliA., Crespo R.,SoldiV.,Fukada K., Macromol.Chem.Phys. vol.205,2004, pp.907.
Fundin J,,Hansson P.,Brown W., Lidegran I.,Macromolecules vo.30, 1997, pp.1118.
Mitra A., Nath A. R., and ChakrabortyA.K.,Colloid Polym Sci. , vol.271,1993, pp.1042.
Panda A.K., Chakraborty A.K., J.Colloid Interface Sci. vol.203,1998, pp.260.
Chakraborty, A.K,.Nath, R.K, Spectrochim Acta vol.45A,1989, pp.981.
Jain N. ,Trabelsi S., Guillot S.,Meloughlin D. ,Langevin D., Leteiller P., Turmine, M., Langmuir, vol..20,2004, pp.8496.
Bakshi M.S., Varga I., GilanyiT.,J.Phys.Chem.B,vol. 109 ,2005, pp.13538.
Balomenou L.,and Bokias G., Langmuir, vol. 21,2005, pp.9038.
Bakshi M.S., and Sachar S.,Colloid Polym.Sci. vol.283,2005,pp.671.
Romani A.P., Gehlen M.H., Itri R., Langmuir, vol.21,2005, pp.127.
Wang C., Tam K.C., Langmuir, vol.18,2002, pp. 6484.
Sjogren H .,Ericsson C.A., Evenas J.,Ulvenlund S .,Biophys J., vol.89,2005, pp.4219 .
Zhu D.M., EvansR.K., Langmuir, 2006, 22 ,pp.3735.
Chatterjee A.,Moulik S.P., Majhi P.R., and Sanyal S.K., Biophys Chem.vol.98,,2002,98, pp.313.
Mata J., Patel J., Jain N.,Ghosh G.,Bahadu, P., J.Colloid Interface Sci. 2006, 297 , pp.797.
Jiao Q.C., Liu Q .,Sun C.,and He H ., Talanta, vol.1095,1999, , pp.48.
Liu Q.,and Jiao Q.C .,Spectrosc.Lett., vol.31,1998, pp.913.
Jiao Q.C. ,and Liu Q.,Spectrochim. Acta, 1vol.55A,999, pp.1667.
Jiao Q.C and Liu Q., Anal.Lett. vol..31,1998, pp.1311.
Jiao Q.C. ,and Liu Q, Spectrosc.Lett.vol.31, 1998, pp.1353.
Hugglin D., Seiffert, A.,Zimmerman, W,Histochemistry, vol.86,1986, pp.71.
Mitra A ., Nath R.K .,and. Chakraborty A.K., Colloid Polym. Sci., vol.271,1993, pp.1042.
Basu. S. , Gupta A.K. ,and Rohatgi-Mukherjee K. K, J.Indian Chem. Soc.1vol.59,982, pp.578 .
Pal M.K., SchubertM.J. Histochem Cytoche., vol.9,1961,pp. 673.
Pal M.K,,and Ghosh B.K., Macromol.Chem, vol.181,1980,pp. 1459.
Pal M.K and Ghosh B.K., Macromol.Chem. vol.180,1979, pp.959.
Pal M.K and Schubert M .,J.Phys.Chem., vol.17,1963,pp.182.
Frank. H.S., and.Evans M.W .,J.Chem.Phys. vol.17,1945, pp.507 .
Kauzmann W.,Advan.Protein.Chem.vol.14, 1959, pp1.
Bruning and Holtzer A., J.Am.Chem Soc.,vol.83,1961, pp.4865.
WhitneyP.L., and Tanford C., J.Biol.Chem vol.237,1962, pp.1735 .
Mukerjee P.,and Ray A. ,J.Phys.Chem. vol.67,1963, pp.190.
Frank H.S. and Quist A.S., J.Chem.Phys.,1vol.34,961, pp.604.
Rabinowitch E ., Epstein.,L.F J.Am.Chem.Soc., vol.63,1941,pp.69.
Romani A.P., Gehlen M.H. and. Itri R., Langmuir, vol.21,2005, pp.127.
Levine A., Schubert M., J.Am.Chem.Soc., vol.74,1958, pp.5702.
Dasgupta S., Nath R.K .,Biswas S., Hossain J., Mitra A.,and Panda A.K. ,Colloids Surf A: Physicochem Eng.Aspects, vol.302,2007, pp.17.
RoseNJ; DragoRS; Journal of American Chemical Society, 1vol.81,959, pp.6138.
Nandini R, Vishalakshi B,e-journal of chemistry, vol.8,2011, pp.S253.
Nandini R, Vishalakshi B,spectrochimica acta Part A,, vol.9,2009, pp.1025
Browse journals by subject